Cover Picture: Evidence of the Lewis‐Amphoteric Character of Tris(pentafluoroethyl)silanide, [Si(C <sub>2</sub> F <sub>5</sub> ) <sub>3</sub> ] <sup>−</sup> (Angew. Chem. Int. Ed. 21/2021)
نویسندگان
چکیده
The tris(pentafluoroethyl)silanide anion adds to carbonyl compounds Ph(R)CO (R=Ph, H), CS2, and CO2, allowing the isolation of novel negatively charged species like [Si(C2F5)3(η2-OC(R)Ph)]− [Si(C2F5)3(η2-CS2)]−, [Si(C2F5)3(η2-CO3)]−. Details reactions are described by Berthold Hoge et al. in their Research Article on page 12124.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202104078